Restyle the web with Stylish, a user styles manager. Stylish lets you easily install themes and skins for Google, Facebook, YouTube, Orkut, and many, many other sites. You can even customize Firefox and other programs themselves.
The Web Developer extension adds various web developer tools to the browser.
As of Firefox 33, Venkman *no longer works*, as the APIs which it needs have been removed.
View HTTP headers of a page and while browsing.
DOM Inspector is a tool that can be used to inspect and edit the live DOM of any web document or XUL application. The DOM can be navigated using a two-paned window displaying a variety of different views on the document and all nodes within.